At present, the whole people enter the era of we-media. As the "indigenous people" of we-media, college students are deeply integrated with we-media and deeply influenced by it. In particular, the conflict of discourses in we-media affects college students' recognition of the socialist core values. On the basis of empirical research and in-depth interviews with some colleges in Shanghai, the paper analyzes the college students’ recognition characteristics of socialist core values, under the impact of the conflict of we-media’s discourses, and analyzes the students' satisfaction and the problems on colleges’ values education with we-media, and puts forward the effective paths for colleges how to use we-media to carry out college students’ education of socialist core values.